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20410419 MS410-Statistical Mechanics in Computational Sciences LM-40 GIULIANI ALESSANDRO
(syllabus)
INTRODUCTION TO STATISTICAL MECHANICS AND GIBBS STATES – The goals of statistical mechanics – Review of thermodynamics. Convex functions and Legendre transform – Models of statistical mechanics: canonical ensemble, grand canonical and Gibbs states. – The Ising model and the lattice gas models. Existence of the thermodynamic limit for the free energy of the Ising or lattice gas model. – The general structure of Gibbs states. Extremal states and mixtures. The notion of phase transition: loss of analyticity and non-uniqueness of the Gibbs state.
THE ISING MODEL – Review of known results on the Ising model in one or more dimensions. – The solution of the one-dimensional Ising model via the transfer matrix method. – The mean field Ising model: exact solution. Phase transition and loss of equivalence between statistical ensembles – Ising with long-range interactions (Kac potentials) in the mean-field limit. The Maxwell construction. – FKG and Griffiths inequalities. Existence of the infinite volume correlation functions of states with + and − conditions in the ferromagnetic Ising model. - The geometric representation of the Ising model: high and low temperature contours. - Existence of a phase transition in the low temperature Ising model: the Peierls's argument. – Absence of a phase transition at high temperature and exponential decay of boundary effects boundary conditions. – Lee-Yang theorem and analyticity of the pressure at non-zero magnetic field. – Existence of a phase transition in the one dimensional Ising model with power law interaction |x − y|^{−p}, 1
(reference books)
S. Friedli, Y. Velenik: Statistical Mechanics of Lattice Systems: a Concrete Mathematical Introduction, Cambridge University Press, 2017.
G. Gallavotti: Statistical Mechanics. A short treatise, ed. Springer-Verlag, 1999.
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