| FUNDAMENTALS OF CHEMISTRY
(objectives)
The course aims to provide students with the tools necessary to frame in a logical and sequential way, not merely descriptive, the main chemical and physico-chemical phenomena related to the microscopic and macroscopic behavior of matter.
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Code
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20802116 |
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Language
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ITA |
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Type of certificate
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Profit certificate
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Credits
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9
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Scientific Disciplinary Sector Code
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CHIM/07
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Contact Hours
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81
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Type of Activity
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Basic compulsory activities
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Group: CANALE 3
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Derived from
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20802116 FUNDAMENTALS OF CHEMISTRY in Mechanical engineering L-9 CANALE 3 DE SANTIS SERENA
(syllabus)
Atom Structure: orbitals, poly-electron atoms, periodic table; bonds in chemistry (Lewis theory and VSEPR, Valence bond theory and hybridization); delocalized bond. Mass relationship in chemical reactions; redox and oxidation number. Solids: metallic, ionic, covalent and molecular crystals (weak bonds: van der Waals and hydrogen bond) Gases: the ideal gas law, gas mixture, Dalton law, partial pressures. Thermodynamics: nature and type of energy, the zero law of T.D., heat capacity, the first law of TD and Enthalphy. Calorimetry and thermochemistry. Born-Haber cycle; Carnot cycle. The second law of TD, Kelvin and Clausius statements, entropy and free energy, equilibrium conditions. Liquids: saturation vapor pressure, Clapeyron law (thermodynamic demonstration), phase change, phase diagrams. Variance. Chemical equilibrium: the equilibrium constant and the equilibrium law, heterogeneous equilibrium, thermal dissociation and dissociation degree. Properties of liquid solutions: concentration units, the Raoult law and distillation, colligatives properties and freezing diagram, electrolytes. Arrhenius, Brönsted and Lewis acids and bases; pH; determination of pH for acidic and basic solutions, salt solutions, buffers.
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Dates of beginning and end of teaching activities
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From 01/03/2016 to 10/06/2016 |
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Delivery mode
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Traditional
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Attendance
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not mandatory
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Evaluation methods
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Written test
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Group: CANALE 5
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Derived from
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20802116 FUNDAMENTALS OF CHEMISTRY in Mechanical engineering L-9 CANALE 5 SOTGIU GIOVANNI
(syllabus)
Atom Structure: orbitals, poly-electron atoms, periodic table; covalent bond, delocalized bond.
Mass relationship in chemical reactions; redox and oxidation number.
Solids: metallic crystal, ionic crystal, molecular crystal, covalent crystal.
Gases: the ideal gas law, partial pressures.
Thermodynamics: nature and type of energy, the zero law of T.D., heat capacity, the first law of TD and Enthalphy, the second law of TD, entropy and free energy, equilibrium conditions.
Liquids: phase change, phase diagrams.
Chemical equilibrium: the equilibrium constant and the equilibrium law
Properties of liquid solutions: concentration units, the Raoult law and distillation, colligatives properties and freezing diagram, electrolytes.
Solutions of strong and weak electrolytes. Acids and bases, pH; Salt hydrolysis; buffer solutions.
(reference books)
Lecture notes
o Depaoli - Chimica Generale ed Inorganica - Ed. Ambrosiana (teoria)
o Silvestroni, Rallo - Problemi di Chimica Generale - Ed. Masson (esercizi)
o Palmisano, Schiavello – Fondamenti di Chimica - EDISES
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Dates of beginning and end of teaching activities
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From 01/03/2016 to 10/06/2016 |
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Delivery mode
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Traditional
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Attendance
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not mandatory
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Evaluation methods
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Written test
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Università Roma Tre