Università Roma Tre

STRUCTURAL THEORY. ISOMERIA AND STEREOISOMERIE. RESONANCE AND ELECTRONIC EFFECTS. FUNCTIONAL GROUPS: STRUCTURE, NOMENCLATURE AND CHEMICAL-PHYSICAL PROPERTIES OF ALCOHOLS, CYCLAALCANS, ALCHENES, ALCHINES, ARENAS, HALOGENURES, ALCOHOLS, AMMINES, IMMINES, PHENOLS, ACIDS, FOREIGN, AMMIDS, IMMIDES AND NITRILE. COMPOUNDS OMO- AND ETHERO-AROMATICS. MAIN MECHANISMS OF REACTION: RADICAL HALOGENIZATION OF THE ALCOHOLS; ELECTROFILED ADDITION TO ALCHENI, DIENI AND ALCHINI; Polymerization; NUCLEOFILY REPLACEMENT (SN1, SN2) AND ELIMINATION (E1 AND E2) TO CARBON SP3; AROMATIC ELECTROPHIL REPLACEMENT; ADDITION NUCLEOFILA TO CARBONY AND REPLACEMENT OF ACRYLIC NUCLEOFILES. SYNTHESIS AND REACTIVITY OF VARIOUS FUNCTIONAL GROUPS IN THE LIGHT OF REACTION MECHANISMS. ENOLATED AND THEIR INTER-, INTRA-MOLECULAR AND CROSS CONDENSATIONS. BI- AND POLIFUNCTIONAL MOLECULES: ACETACETIC AND MALONIC SYNTHESIS; HYDROXYCYCLES, ENONIC SYSTEMS, TRIGLYCERIDES (SOAPS, SURFACTANTS AND MICELLAS), ALFA-AMINO ACIDS (STRUCTURES AND ISOELETTRIC POINT), CARBOHYDRATES (CLASSIFICATION, EMIACETALIC STRUCTURES, GLUCOSIDES, POLYSACCHARIDES).